Adhesives and Sealants
Volatile Organic Compound (VOC) Content Limits
Introduction
This document summarizes the regulations in several states affecting the content limits of Volatile Organic Compounds (VOCs) for Adhesives and Sealants. For a quick introduction on how to most easily interpret these pages, link to How to Use the VOC and MIR Rules.
Skip to regulations:
- South Coast Air Quality Management District (SCAQMD)
- California Air Resources Board
- Massachusetts
- Texas
- Ozone Transport Commission (OTC) (NY, NJ)
- Lake Michigan Air Directors Consortium (LADCO) (MI, OH, IL, IN)
South Coast Air Quality Management District (SCAQMD)
Typically, SCAQMD has the tightest and most comprehensive VOC regulations. It has enacted the following regulation: Rule 1168 (PDF) Adhesive and Sealant Applications It has been amended several times, the last time in 2005. SCAQMD has convened a working group to propose stricter regulations to come into effect in 2015, followed by a further tightening in 2016 and 2018. Here are the current rules and proposed changes:
Sources:
Rule 1168; http://www.aqmd.gov/docs/default-source/rule-book/Proposed-Rules/1168/par1168_051614.pdf?sfvrsn=2
Architectural Applications
Application | Current VOC Limit (g/liter) | Proposed Limit Effective 1/1/15 | Proposed Limit Effective 1/1/16 | Proposed Limit Effective 1/1/18 | Proposed Limit Effective 1/1/19 |
Adhesives: | |||||
ABS Welding | 325 | ||||
ABS to PVC Transition Cement | 510 | ||||
Indoor Carpet | 50 | ||||
Carpet Pad | 50 | 20 | |||
Outdoor Carpet | 150 | ||||
Outdoor Floor Covering | 150 | 20 | |||
Wood Flooring | 100 | 50 | 20 | ||
Indoor Flooring | 50 | 20 | |||
Rubber Floor | 60 | 20 | |||
Subfloor | 50 | 20 | |||
Ceramic Tile | 65 | 20 | |||
VCT and Asphalt Tile | 50 | 20 | |||
Dry Wall and Panel | 50 | 40 | |||
Cove Base | 50 | 20 | |||
Multipurpose Construction | 70 | 40 | 20 | ||
Structural Wood Member | 140 | 50 | |||
Structural Glazing | 100 | 40 | |||
Single Ply Roof Membrane Adhesive | 250 | 100 | |||
Other Roof Adhesive | 250 | 100 | |||
Welding | |||||
CPVC Welding | 490 | ||||
Plastic Cement Welding | 250 | ||||
PVC Welding | 510 | ||||
Other Adhesive | |||||
Rubber Vulcanization | 850 | ||||
Special Purpose Contact | 250 | ||||
Contact | 80 | ||||
Top and Trim | 250 | 540 | ?? | ||
All Other Adhesives | 250 | ||||
Other Applications | |||||
Computer Diskette Manufacturing | 350 | ||||
Thin Metal Laminating | 780 | ||||
Tire (re)Tread | 100 | ||||
Waterproof Resorcinal Glue | 170 | ||||
Sheet Applied Rubber Lining Operations | 850 | ||||
Substrate Specific Adhesive Applications | |||||
Metal | 30 | ||||
Plastic Foams | 50 | 20 | |||
Porous Materials (except wood) | 50 | ||||
Wood | 30 | ||||
Fiberglass | 80 | ||||
Reinforced Plastic Composite | 250 | 200 | |||
Other Substrates | 250 | ||||
Sealants and Caulks | |||||
Architectural | |||||
Clear, Paintable, Immediately Water Resistant | 250 | 380 | 50 | ||
Foam Sealant | 250 | 200 | 20 | ||
Marine Deck | 760 | ||||
Potable Water | 250 | 100 | |||
All Other Roof | 300 | 100 | |||
Single Ply Roof Membrane | 450 | 100 | |||
Other Roof Sealant | 300 | 100 | |||
All Other Architectural | 250 | 50 | |||
Roadway | 250 | 50 | |||
All Other Sealants | 420 | ||||
Adhesive Primers | |||||
Plastic | 550 | ||||
Pressure Sensitive | 785 | ||||
Traffic Marking Tape | 150 | ||||
Vehicle Glass | 700 | ||||
All Other Adhesive Primers | 250 | ||||
Sealant Primers | |||||
Architectural | |||||
Non Porous | 250 | ||||
Porous | 775 | ||||
Marine Deck | 760 | ||||
Modified Bituminous | 500 | ||||
All Other Sealant Primers | 750 |
Adhesives and Sealants Regulations Enacted by other Jurisdictions
California Air Resources Board (CARB):
The California Code of Regulations (CCR) Title 17, Division 3 Chapter 1 – Air Resources Board Subchapter 8.5 – Consumer Products Article 2 regulates VOC emissions from all consumer products, including some adhesive products. Note that CARB is revising the regulations for Aerosol consumer products, including some Adhesive Products.
Here are the applicable regulations and proposed changes for Aerosol Adhesives:
Consumer Products Aerosol – Adhesive | Current VOC Limit % by weight | New VOC Limit % by weight | Effective Date |
Mist Spray Adhesive | 65 | 30 | 1/1/2017 |
Screen Printing Adhesive | 55 | 55 | 1/1/2017 |
Web Spray Adhesive | 55 | 40 | 1/1/2017 |
Here are the Regulations for other Adhesives and Sealants:
Consumer Product | VOC Limit (% by Weight) |
Special Purpose Spray Adhesive | |
Mounting, Automotive Engine Compartment, and Flexible Vinyl Adhesive | 70 |
Polystyrene Foam and Automobile Headliner Adhesive | 65 |
Polyolefin and Laminate Repair/Edgebanding Adhesive | 60 |
Contact Adhesive – General Purpose | 55 |
Contact Adhesive – Special Purpose | 80 |
Adhesive Remover | |
Floor or Wall Covering Adhesive Remover | 5 |
Gasket or Thread Locking Adhesive Remover | 50 |
General Purpose Adhesive Remover | 20 |
Specialty Adhesive Remover | 70 |
Sealant or Caulking Compound | |
All forms | 4 |
Chemically Curing nonaerosol | 3 |
Nonchemically Curing nonaerosol | 1.5 |
Many states and jurisdictions have adopted the CARB limits as they currently exist in late 2014, as described below. CARB is diligent in enforcing its regulations.
Massachusetts
Massachusetts air pollution control regulations are contained in: 310 CMR 7.00: Air Pollution Control Regulations. Section 7.18: Volatile & Halogenated Organic Compounds, starting at page 269, is a detailed regulation governing the VOC content of a wide range of known emitters. Section 7.18 recently added a new section (30): Adhesives, Adhesive Primers, Sealants and Sealant Primers to the list of regulated products. Limits came into effect on January 1, 2015 and more come into effect January 1, 2016.
Source: http://www.mass.gov/eea/docs/dep/service/regulations/proposed/adhpregr.doc
Adhesive, Sealant, Adhesive Primer Or Sealant Primer Category | VOC Content Limit (grams/liter*) |
ABS Welding | 400 |
Ceramic Tile Installation | 130 |
Computer Diskette Jacket Manufacturing | 850 |
Contact | 250 |
Cove Base Installation | 150 |
CPVC Welding | 490 |
Indoor Floor Covering Installation | 150 |
Metal to Urethane/Rubber Molding Or Casting | 850 |
Multipurpose Construction | 200 |
Nonmembrane Roof Installation/Repair | 300 |
Outdoor Floor Covering Installation | 250 |
Perimeter Bonded Sheet Vinyl Flooring Installation | 660 |
Plastic Cement Welding (Non ABS) | 500 |
PVC Welding | 510 |
Sheet Rubber Lining Installation | 850 |
Single-ply Roof Membrane Installation/Repair | 250 |
Structural Glazing | 100 |
Thin Metal Laminating | 780 |
Tire Retread | 100 |
Waterproof Resorcinol Glue | 170 |
Sealants | |
Architectural | 250 |
Marine Deck | 760 |
Nonmembrane Roof Installation/Repair | 300 |
Roadway | 250 |
Single-ply Roof Membrane | 450 |
Other | 420 |
Adhesive Primers | |
Automotive Glass | 700 |
Plastic Cement Welding | 650 |
Single-ply Roof Membrane | 250 |
Traffic Marking Tape | 150 |
Other | 250 |
Sealant Primers | |
Non-porous Architectural | 250 |
Porous Architectural | 775 |
Marine Deck | 760 |
Other | 750 |
VOC Content Limit for Adhesives Applied to Particular Substrate | VOC Content Limit (grams/liter*) |
Substrate Category | |
Flexible Vinyl | 250 |
Fiberglass | 200 |
Metal | 30 |
Porous Material | 120 |
Reinforced Plastic Composite | 200 |
Rubber | 250 |
Wood | 30 |
Other Substrates | 250 |
Note: The new Table 1 contained in 310 CMR 7.00: Air Pollution Control Regulations showing the new VOC content limits for Adhesive and Sealant products starting on page 355 is garbled. When it is updated, it will be added to this section. A comparison of the SCAQMD and Massachusetts tables reveals that the SCAQMD proposed new regulations are significantly tougher.
Texas
The Texas Administrative Code, Title 30 Environmental Quality, Part 1 Texas Commission on Environmental Quality, Chapter 115 Control Of Air Pollution From Volatile Organic Compounds, Division 7: Miscellaneous Industrial Adhesives, includes regulations on emissions from Adhesives products which came into effect on March 1, 2013. However, there are no regulations on the VOC content limits of Adhesive products. The VOC Content Limits are included in the following table: Source: http://info.sos.state.tx.us/fids/201105434-3.html Figure: 30 TAC §115.473(a)
Table 1. | |
General Adhesive Application Processes | Pounds of volatile organic compounds per gallon adhesive |
Reinforced Plastic Composite | 1.7 |
Flexible vinyl | 2.1 |
Metal | 0.3 |
Porous Material (Except Wood) | 1.0 |
Rubber | 2.1 |
Wood | 0.3 |
Other Substrates | 2.1 |
Table 2. | |
Specialty Adhesive Application Processes | Pounds of volatile organic compounds per gallon adhesive |
Ceramic Tile Installation | 1.1 |
Contact Adhesive | 2.1 |
Cove Base Installation | 1.3 |
Floor Covering Installation (Indoor) | 1.3 |
Floor Covering Installation (Outdoor) | 2.1 |
Floor Covering Installation (Perimeter Bonded Sheet Vinyl) | 5.5 |
Metal to Urethane/Rubber Molding or Casting | 7.1 |
Motor Vehicle Adhesive | 2.1 |
Motor Vehicle Weatherstrip Adhesive | 6.3 |
Multipurpose Construction | 1.7 |
Plastic Solvent Welding acrylonitrile butadiene styrene (ABS) | 3.3 |
Plastic Solvent Welding (Except ABS) | 4.2 |
Sheet Rubber Lining Installation | 7.1 |
Single-Ply Roof Membrane Installation/Repair (Except Ethylene Propylene Diene Monomer) | 2.1 |
Structural Glazing | 0.8 |
Thin Metal Laminating | 6.5 |
Tire Repair | 0.8 |
Waterproof Resorcinol Glue | 1.4 |
Table 3. | |
Adhesive Primer Application Processes | Pounds of volatile organic compounds per gallon adhesive |
Motor Vehicle Glass-Bonding Primer | 7.5 |
Plastic Solvent Welding Adhesive Primer | 5.4 |
Single-Ply Roof Membrane Adhesive Primer | 2.1 |
Other Adhesive Primer | 2.1 |
If the manufacturer cannot comply with the content limits, he may instead operate a vapor control system capable of achieving an overall control efficiency of 85% of the VOC emissions from adhesives and adhesive primers.
Ozone Transport Commission (OTC)
The OTC states: Connecticut, Delaware, the District of Columbia, Maine, Maryland, Massachusetts, New Hampshire, New Jersey, New York, Pennsylvania, Rhode Island, Vermont, and Virginia, adopted Model Rule 2006 – Adhesives and Sealantsin 2009 which includes the following table of VOC content limits: Table 1. VOC Content Limits for Adhesives, Sealants, Adhesive Primers, Sealant Primers and Adhesives Applied to Particular Substrates Source: http://www.otcair.org/upload/Documents/Model%20Rules/OTC_Adhesives_and_Sealants_Model_Rule_Final.doc These limits are very similar to the limits adopted by Massachusetts and so are less strict than SCAQMD.
New York
New York has adopted VOC Content rules for Adhesives that mirror the CARB standards.
In addition, it has adopted specific rules under Subpart 228-2 Commercial and Industrial Adhesives, Sealants and Primers. Table 1. VOC Content Limits for Adhesives, Sealants, Adhesive Primers, Sealant Primers and Adhesives Applied to the Listed Substrates
Adhesive, Sealant, Adhesive Primer or Sealant Primer Category | VOC Content Limit (grams/liter*) |
Adhesives | |
ABS welding | 400 |
Ceramic tile installation | 130 |
Computer diskette jacket manufacturing | 850 |
Contact bond | 250 |
Cove base installation | 150 |
CPVC welding | 490 |
Indoor floor covering installation | 150 |
Metal to urethane/rubber molding or casting | 850 |
Multipurpose construction | 200 |
Nonmembrane roof installation/repair | 300 |
Other plastic cement welding | 510 |
Outdoor floor covering installation | 250 |
PVC welding | 510 |
Single-ply roof membrane installation/repair | 250 |
Structural glazing | 100 |
Thin metal laminating | 780 |
Tire retread | 100 |
Perimeter bonded sheet vinyl flooring installation | 660 |
Waterproof resorcinol glue | 170 |
Sheet-applied rubber installation | 850 |
Sealants | |
Architectural | 250 |
Marine deck | 760 |
Nonmembrane roof installation/repair | 300 |
Roadway | 250 |
Single-ply roof membrane | 450 |
Other | 420 |
Adhesive Primers | |
Automotive glass | 700 |
Plastic cement welding | 650 |
Single-ply roof membrane | 250 |
Traffic marking tape | 150 |
Other | 250 |
Sealant Primers | |
Non-porous architectural | 250 |
Porous architectural | 775 |
Marine deck | 760 |
Other | 750 |
Adhesives Applied to the Listed Substrate | |
Flexible vinyl | 250 |
Fiberglass | 200 |
Metal | 30 |
Porous material | 120 |
Rubber | 250 |
Other substrates | 250 |
New Jersey
The New Jersey Administrative Code, Title 7, Chapter 27, Air Pollution Control includes Subchapter 26 Prevention of Air Pollution from Adhesives, Sealants, Adhesive Primers and Sealant Primers enacted in 2011. The regulations are captured in the following table:
Table 1. VOC Content Limits for Adhesives, Sealants, Adhesive Primers, Sealant Primers and Adhesives Applied to Particular Substrates
Source: http://www.state.nj.us/dep/aqm/Sub26.doc
These limits are very similar to the limits adopted by Massachusetts and so are less strict than SCAQMD.
The Lake Michigan Air Directors Consortium (LADCO)
Indiana, Illinois, Michigan, Wisconsin and Ohio, implemented VOC control strategy to adopt SCAQMD and CARB rules as appropriate.
- Ohio has adopted the CARB regulations for certain Adhesive products: Table 1: Table of standardsSource: http://www.epa.ohio.gov/portals/27/regs/3745-112/3745-112-03_Final.pdf
- Illinois: Illinois specifically incorporates California Code Section 41712(h)(2) for Adhesives and Sealants.
- Indiana: includes VOC content limits very similar to those of Ohio.
Summary: Jurisdictions that regulate the VOC Content of Adhesives and Sealants can be grouped into 3 categories by strictness: Toughest: SCAQMD Next Toughest: CARB (and the jurisdictions that follow them, including New York, Ohio and Indiana) Less Strict: Massachusetts (and the jurisdictions that follow them, including the OTC and LADCO states) It is not clear whether regulations of most states will gravitate towards SCAQMD or CARB, given that many have recently adopted less strict rules, such as Massachusetts.Solvent users need to determine where the Adhesive and Sealant products will be manufactured and sold. If the products are made or sold into SCAQMD, and have not been reformulated to comply with the new restrictions, the manufacturer may need to accelerate its reformulation programs, and they have only until January 1, 2016. TBF can help.If they are not planning to sell into SCAQMD, they may choose to comply with the less strict regulations, however, reformulation with TBF Zero VOC solvents may still be necessary.